I applied through an employee referral. The process took 2 days. I interviewed at Goodwill (Rochester, PA) in Jan 2012
Interview
You come in for two interviews. The first is just the question-and-answer bit, and the second is a drug screen (which is only a swab). Be careful if you're young--the bosses there are looking for older people because they're tired of dealing with "kids," so they've been hiring people older than middle-age (as of 9/12/2012).
Interview questions [1]
Question 1
Standard retail questions. "Give me an example of a time when..." type of things. Easy.